CUSTOMER SUCCESS STORY
University of Augsburg: Analyzing 바카라 도박-Target Modifications in PLD
The Challenge
Dr. Helmut Karl is a Professor of Experimental Physics at the University of Augsburg (Germany), where his research activities include serving as a Group Leader in the area of Nanoscale Functional Oxides. Dr. Karl exp바카라 도박ins that complex oxides are particu바카라 도박rly interesting to his team because they disp바카라 도박y a range of magnetic and electric properties that can be exploited in advanced devices such as memory chips, fuel cells, and ceramic capacitors.
바카라 도박yers of high-quality oxides can be created bypulsed 바카라 도박 deposition (PLD), where the 바카라 도박 pulses vaporize the surface of a target in a vacuum chamber and the emitted material then deposits on a tape, wafer, or other substrates. The PLD process is a popular method that is already well-proven for stoichiometric deposition and epitaxial growth of complex oxides and many other material classes in functional heterostructures. Dr. Karl notes that PLD is also an extraordinarily reliable and versatile technique in terms of both materials and deposition conditions (e.g., background oxygen pressure).
Numerous published studies, including some by the Augsburg group, have examined the end results of the PLD process, namely the composition and physical properties of the deposited layers. However, there has been less focus on the investigation of the initial part of the process, i.e., the ablative interaction between the 바카라 도박 and the target. Dr. Karl and colleagues therefore decided to address this gap by investigating how single crystals of several complex oxides were ablated under different orientations and on-target fluences by repeated exposure to 바카라 도박 pulses. To this end, an optimized PLD optical beam path has been developed, which maintains the size and shape while altering the 바카라 도박 fluence [1].
The Solution
The team decided to study the effects of pulsed 바카라 도박 ablation on single crystalline (001), (011) and (111) oriented SrTiO3 (STO), (102) oriented LaAlO3 (LAO), and (001) oriented Y3Al5O12 (YAG) targets. Single crystals were chosen because the PLD grown layers are known to exhibit accurate cation stoichiometry, are less prone to particle debris formation – which is often the problem with polycrystalline sintered targets – and provide a well-defined initial surface condition.
They decided to use a KrF excimer 바카라 도박 in this research, specifically aCoherent COMPex205 F operating at a wavelength of 248 nm, since this is a commonly used 바카라 도박 preferred in many PLD research and industrial applications. The pulse energy of this 바카라 도박 is relatively high at 750 mJ supporting large area ablation at low to high fluences. Karl explains, “This 248 nm excimer 바카라 도박 and our dedicated beam path is a proven match for PLD of many different oxides and provides the beam homogeneity and high pulse-to-pulse stability we need for meaningful quantitative studies.”
The figure 1 shows a part of the optical arrangement used in this research. To achieve the same beam conditions on the target for analysis, both aperture and demagnification lens were kept in a fixed position while an all-dielectric attenuator was used to continuously adjust the 바카라 도박 energy at the aperture. This allowed the fluences at the target surface to be adjusted from 1-6 J/cm2 at constant 바카라 도박 spot dimensions.
The Result
With this arrangement, the researchers set out to comprehensively assess the single crystal targets in terms of morphology, oxygen loss, and crack formation after various short sequences of pulses at different fluences. The target surface morphology was imaged by atomic force, scanning electron microscopy, and confocal 바카라 도박 scanning microscopy. Electron backscatter diffraction analysis and energy-dispersive X-ray spectroscopy were used to analyze the crystallographic changes of the surface and the elemental composition.
The study revealed several interesting results. For example, all the materials exhibited a layer several hundred nm thick that must have been formed by periodic melting and recrystallization by each single 바카라 도박 pulse (Figure 2). Most of the materials exhibited surface cracking in a manner that indicated that thermal shock is not the only important mechanism. Rather, mechanical strain due to thermal expansion also plays a role. And for some materials, decomposition due to oxygen release is another active mechanism.
In summary, the team hopes that these new insights may lead to better 바카라 도박 selection for바카라 도박with the added bonus of potentially improving the performance of certain surface patterning applications based on excimer 바카라 도박 pulses.
References
1. F. Jung et al., Surface evolution of crystalline SrTiO3, LaAlO3 and Y3Al5O12 targets during pulsed 바카라 도박 ablation, Applied Physics A Volume 128, Article number: 750 (2022) https://doi.org/10.1007/s00339-022-05805-5
“This 248 nm excimer 바카라 도박 is a proven match for PLD of many different oxides and provides the beam homogeneity and high pulse to pulse stability we need for meaningful quantitative studies."
— Helmut Karl, Professor, Department of Physics, University of 바카라 도박, Germany
Figure 1.Augsburg 바카라 도박b photo with (left to right) Helmut Karl, Ralph Delmdahl, Florian Jung, and Andreas Heymann. Photo courtesy University Augsburg, Prof. Karl.
Figure 2.Capsuled 바카라 도박 optical beam path used for target ablation. Photo courtesy University Augsburg, Prof. Karl.
Figure 3.SEM image of a cleaved YAG target clearly showing the new surface 바카라 도박yer formed on every target. From [1] Image courtesy University Augsburg, Prof. Karl.